Sodium CarboxymethylCellulose

Cellulose Ethers

Sodium CarboxymethylCellulose

Sodium Carboxymethyl Cellulose (CMC) is an anionic water-soluble polymer that is produced by chemically modifying cellulose. CMC is produced by reacting alkali cellulose (cellulose treated with sodium hydroxide) with sodium monochloroacetate. This chemical reaction introduces carboxymethyl groups (-CH2COOH) onto the cellulose backbone, which makes the cellulose water-soluble. The degree of substitution (DS), which refers to the average number of carboxymethyl groups per anhydroglucose unit in the cellulose molecule, influences the properties of the CMC.

Water Solubility

CMC is highly soluble in both cold and hot water, forming clear to translucent solutions.

Thickening Agent

It’s an excellent thickener and viscosity modifier. It forms viscous solutions even at low concentrations.

Stabilizer

It acts as a stabilizer in emulsions and suspensions, preventing phase separation and sedimentation.

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How it's made?

CMC is produced by reacting alkali cellulose (cellulose treated with sodium hydroxide) with sodium monochloroacetate. This chemical reaction introduces carboxymethyl groups (-CH2COOH) onto the cellulose backbone, which makes the cellulose water-soluble. The degree of substitution (DS), which refers to the average number of carboxymethyl groups per anhydroglucose unit in the cellulose molecule, influences the properties of the CMC.

Key properties and uses

The versatility of CMC stems from its unique combination of properties:

  • Water Solubility: CMC is highly soluble in both cold and hot water, forming clear to translucent solutions.
  • Thickening Agent: It’s an excellent thickener and viscosity modifier. It forms viscous solutions even at low concentrations.
  • Stabilizer: It acts as a stabilizer in emulsions and suspensions, preventing phase separation and sedimentation.
  • Binder: It can bind particles together, improving the integrity and strength of various products.
  • Film Former: It can form clear, flexible films upon drying.
  • Water Retention Agent: Similar to pregelatinized starch, CMC can significantly improve water retention.
  • Suspending Agent: It helps to keep insoluble particles suspended in a liquid, preventing them from settling.
  • Protective Colloid: It can form a protective layer around dispersed particles, preventing aggregation.
  • Non-toxic and Biodegradable: CMC is generally recognized as safe (GRAS) for food and pharmaceutical applications and is biodegradable.
Typical Applications
  • CMC finds extensive use across a wide range of industries:

    • Food Industry:
      • Thickener and Stabilizer: In ice cream (prevents ice crystal formation), yogurts, sauces, dressings, beverages, and baked goods.
      • Binder: In processed meats and vegetarian patties.
      • Texture Modifier: Improves mouthfeel and consistency.
    • Pharmaceutical Industry:
      • Binder and Disintegrant: In tablets and capsules.
      • Suspending Agent: In liquid medications.
      • Viscosity Modifier: In eye drops and topical creams.
    • Cosmetics and Personal Care:
      • Thickener and Stabilizer: In shampoos, lotions, creams, toothpastes, and detergents.
      • Emulsifier: Helps to blend oil and water components.
    • Paper Industry:
      • Sizing Agent: Improves strength, printability, and surface smoothness of paper.
      • Binder: In paper coatings.
    • Textile Industry:
      • Sizing Agent: Improves yarn strength and reduces breakage during weaving.
      • Thickener: In textile printing pastes.
    • Construction Industry:
      • Water Retention Agent and Thickener: In cement-based products like tile adhesives, grouts, and wall putty (as mentioned in our previous discussion). It improves workability and reduces cracking.
    • Drilling Fluids:
      • Viscosity Modifier and Fluid Loss Control: In oil and gas drilling, it helps to control the viscosity of drilling muds and prevent fluid loss into porous rock formations.

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